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We shown that, in contrast to classical
two.2]decane Main and defining the geometry of your exocyclic double bond. The activation energies of development on the vinyl-gold intermediates had been calculated and discovered a silyl enol ether with the unprotected indole moiety as a suitable precursor for that Toste cyclization. This 6-mo
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The initial asymmetric overall synthesis of conolidine was made by Mica
2.2]decane core and defining the geometry of your exocyclic double bond. The activation energies of formation in the vinyl-gold intermediates have been calculated and uncovered a silyl enol ether with the unprotected indole moiety as an appropriate precursor for that Toste cyclization. This six-